The mother-of-one arrived alongside her husband William at High Street Kensington tube station, with her brunette locks shaded by a hint of silver streaks at the roots.
Usually sporting a head of glossy chocolate locks, it looked as though Kate had forgotten to touch up her roots as an array of silver strands were clearly visible.
And that wasn't the only change for the Duchess, who also debuted a new hairstyle during her day out in the capital.Blow-dried into an edgy middle parting, Kate replaced her usual voluminous side sweep which has inspired so many blow-dries throughout the UK.
Looking over the moon with her subtle new look, which saw her trademark curls still firmly in place, the Duchess smiled proudly for the barrage of awaiting photographers who couldn't wait to catch her new look on camera.
Laughing and joking with her husband and members of the public, it looked as though Kate couldn't have been more confident with her new 'do - which was no doubt styled by her recently-hired hairdresser, Joh Bailey, who styled Princess Diana's hair.
And there is no doubt that the brunette has set the fashion elite's tongues wagging after ditching her signature look in favour of a much more fashion-forward style.
But, aside from her new tresses, Kate remained her usual impeccable self as she made her way through the Capital on an array of public transport.
Opting for a stylish LK Bennett red coat, the new mother looked every inch the yummy mummy as she teamed it with black tights and a pair of black heels.
The new parents headed to the station in a bid to boost poppy sellers profits, after the Royal British Legion launched efforts to help raise £1million for forces charities in a single day.
The couple were mobbed by astonished travellers who couldn't believe their luck when they ran into the royal pair.
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